利用源自农业和工业废弃物的低成本吸附剂去除水中的莠去津。

Removal of atrazine from water by low cost adsorbents derived from agricultural and industrial wastes.

作者信息

Sharma Rajendra Kumar, Kumar Anoop, Joseph P E

机构信息

Department of Chemistry, School of Chemical Sciences, St. John's College, Agra 282002, India.

出版信息

Bull Environ Contam Toxicol. 2008 May;80(5):461-4. doi: 10.1007/s00128-008-9389-6. Epub 2008 Mar 21.

Abstract

In the present study six adsorbents viz. wood charcoal, fly ash, coconut charcoal, saw dust, coconut fiber and baggasse charcoal were studied for their capacity to remove atrazine from water. The removal efficiency of different adsorbents varied from 76.5% to 97.7% at 0.05 ppm concentration and 78.5% to 95.5% at 0.1 ppm concentration of atrazine solution, which was less than removal efficiency of activated charcoal reported as 98% for atrazine (Adams and Watson, J Environ Eng ASCE 39:327-330, 1996). Wood charcoal was a cheap (Rs 15 kg(-1)) and easily available material in house holds. Since wood charcoal was granular in nature, it could be used for the removal of atrazine from water to the extent of 95.5%-97.7%. Fly ash is a waste product of thermal plant containing 40%-50% silica, 20%-35% alumina, 12%-30% carbon and unburnt minerals having a high pH of 9-10. It is very cheap and abundant material and has comparatively good adsorption capacity. It was found that fly ash effectively removed about 84.1%-88.5% atrazine from water at 0.05 and 0.1 ppm levels. Coconut shell is also waste product. Therefore, both are inexpensive. The removal efficiency of atrazine from water was 92.4%-95.2% by coconut shell charcoal and 85.9%-86.3% by coconut fiber. Sawdust is generally used as domestic fuel and found everywhere. It is also very cheap (Re. 1 kg(-1)). Baggasse charcoal is a waste product of sugar mill and abundant material. Its cost is due to transport expense, which depends upon distance from the sugar mill. The removal efficiency of sawdust and baggasse charcoal was found 78.5-80.5 and 76.5-84.6, respectively. The efficacy of chemically treated adsorbents for the removal of atrazine from water is in the order: wood charcoal > coconut shell charcoal > fly ash > coconut fiber charcoal > baggasse charcoal > sawdust.

摘要

在本研究中,对六种吸附剂,即木炭、粉煤灰、椰壳炭、锯末、椰纤维和蔗渣炭去除水中莠去津的能力进行了研究。在莠去津溶液浓度为0.05 ppm时,不同吸附剂的去除效率在76.5%至97.7%之间;在浓度为0.1 ppm时,去除效率在78.5%至95.5%之间,这低于活性炭对莠去津的去除效率(据报道为98%)(亚当斯和沃森,《环境工程杂志》美国土木工程师学会39:327 - 330,1996年)。木炭价格便宜(15卢比/千克),在家庭中很容易获得。由于木炭本质上是颗粒状的,它可用于去除水中的莠去津,去除率可达95.5% - 97.7%。粉煤灰是热电厂的一种废弃物,含有40% - 50%的二氧化硅、20% - 35%的氧化铝、12% - 30%的碳以及未燃烧的矿物质,其pH值高达9 - 10。它非常便宜且储量丰富,具有相对较好的吸附能力。研究发现,粉煤灰在0.05和0.1 ppm水平下能有效去除水中约84.1% - 88.5%的莠去津。椰壳也是废弃物。因此,两者都价格低廉。椰壳炭对水中莠去津的去除效率为92.4% - 95.2%,椰纤维为85.9% - 86.3%。锯末通常用作家庭燃料,随处可见。它也非常便宜(1卢比/千克)。蔗渣炭是糖厂的废弃物,储量丰富。其成本主要是运输费用,这取决于与糖厂的距离。锯末和蔗渣炭对莠去津的去除效率分别为78.5 - 80.5和76.5 - 84.6。经化学处理的吸附剂去除水中莠去津的效果顺序为:木炭>椰壳炭>粉煤灰>椰纤维炭>蔗渣炭>锯末。

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