Banerjee Arghya, Das Biswajit
Nevada Nanotechnology Center, Howard R. Hughes College of Engineering, University of Nevada, Las Vegas, Nevada 89154-4026, USA.
Rev Sci Instrum. 2008 Mar;79(3):033910. doi: 10.1063/1.2885042.
Nanoparticles of metals and semiconductors are promising for the implementation of a variety of photonic and electronic devices with superior performances and new functionalities. However, their successful implementation has been limited due to the lack of appropriate fabrication processes that are suitable for volume manufacturing. The current techniques for the fabrication of nanoparticles either are solution based, thus requiring complex surface passivation, or have severe constraints over the choice of particle size and material. We have developed an ultrahigh vacuum system for the implementation of a complex nanosystem that is flexible and compatible with the silicon integrated circuit process, thus making it suitable for volume manufacturing. The system also allows the fabrication of Ohmic contacts and isolation dielectrics in an integrated manner, which is a requirement for most electronic and photonic devices. We have demonstrated the power and the flexibility of this new system for the manufacturing of nanoscale devices by implementing a variety of structures incorporating nanoparticles. Descriptions of this new fabrication system together with experimental results are presented in this article. The system explains the method of size-selected deposition of nanoparticles of any metallic, semiconducting, and (or) insulating materials on any substrate, which is very important in fabricating useful nanoparticle-based devices. It has also been shown that at elevated substrate temperature, a selective deposition of the nanoparticles is observed near the grain-boundary regions. However, in these natural systems, there will always be low and favorable energy states present away from the grain-boundary regions, leading to the undesirable deposition of nanoparticles in the far-grain-boundary regions, too.
金属和半导体纳米粒子有望用于实现各种具有卓越性能和新功能的光子和电子器件。然而,由于缺乏适用于批量制造的合适制造工艺,它们的成功应用受到了限制。目前制造纳米粒子的技术要么基于溶液,因此需要复杂的表面钝化,要么在粒径和材料选择上有严格限制。我们开发了一种超高真空系统,用于实现一个复杂的纳米系统,该系统灵活且与硅集成电路工艺兼容,从而适合批量制造。该系统还允许以集成方式制造欧姆接触和隔离电介质,这是大多数电子和光子器件的一项要求。我们通过实现包含纳米粒子的各种结构,展示了这种用于制造纳米级器件的新系统的能力和灵活性。本文介绍了这种新制造系统及其实验结果。该系统解释了在任何衬底上对任何金属、半导体和(或)绝缘材料的纳米粒子进行尺寸选择沉积的方法,这在制造有用的基于纳米粒子的器件中非常重要。还表明,在升高的衬底温度下,在晶界区域附近观察到纳米粒子的选择性沉积。然而,在这些自然系统中,远离晶界区域总会存在低能量且有利的状态,这也导致纳米粒子在远晶界区域出现不期望的沉积。