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通过同时萃取/蒸馏法从摩洛哥黑橄榄中获得的提取物中气味活性化合物的表征

Characterization of odor-active compounds in extracts obtained by simultaneous extraction/distillation from moroccan black olives.

作者信息

Collin Sonia, Nizet Sabrina, Muls Sophie, Iraqi Rafika, Bouseta Amina

机构信息

Unité de Brasserie et des Industries Alimentaires, Université catholique de Louvain, Croix du Sud 2/Bte 7, B-1348 Louvain-la-Neuve, Belgium.

出版信息

J Agric Food Chem. 2008 May 14;56(9):3273-8. doi: 10.1021/jf073488x. Epub 2008 Apr 5.

Abstract

"Greek-style" Moroccan black table olives were screened for potent odorants by GC/olfactometry/aroma extract dilution analysis of representative Likens-Nickerson extracts and compared with "Spanish-style" green fruits. ( Z)-3-Hexenal, ( E, E)-2,4-decadienal, ( E, Z)-2,4-decadienal, guaiacol, and methional were found in both green and black olives, but with significant differences in concentration according to the fruit ripening degree (the first was lower and the last two were higher in black fruits). Specific compounds not previously detected in green olives (gamma-deca- and dodecalactones, delta-decalactone, and 2-methyl-3-furanthiol) proved to be, with methional, the strongest odors in black olive extracts. These extracts were also distinguishable from green olive extracts by the presence of new sulfur compounds and fewer terpenes.

摘要

通过对代表性的利肯斯-尼克森提取物进行气相色谱/嗅觉测定/香气提取物稀释分析,对“希腊风格”的摩洛哥黑橄榄进行了强力气味物质筛选,并与“西班牙风格”的青橄榄进行了比较。在青橄榄和黑橄榄中均发现了(Z)-3-己烯醛、(E,E)-2,4-癸二烯醛、(E,Z)-2,4-癸二烯醛、愈创木酚和甲硫醛,但根据果实成熟度,其浓度存在显著差异(第一种在黑果中较低,后两种在黑果中较高)。以前在青橄榄中未检测到的特定化合物(γ-癸内酯和十二内酯、δ-癸内酯和2-甲基-3-呋喃硫醇)与甲硫醛一起,被证明是黑橄榄提取物中气味最强的物质。这些提取物还因新的硫化合物的存在和较少的萜类化合物而与青橄榄提取物有所区别。

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