Western Regional Research Center, Agricultural Research Service, U.S. Department of Agriculture, 800 Buchanan Street, Albany, CA 94710, United States; Department of Food Science and Technology, University of California, One Shields Avenue, Davis, CA 95616, United States.
Food Chem. 2014 Apr 15;149:285-95. doi: 10.1016/j.foodchem.2013.10.090. Epub 2013 Oct 31.
Volatile constituents of commercial black-ripe table olives (Olea europaea) from the United States, Spain, Egypt and Morocco were analysed by gas chromatography and gas chromatography-mass spectrometry (GC-MS). Dynamic headspace sampling was used to isolate a variety of aldehydes, alcohols, esters, ketones, phenols, terpenes, norisoprenoids, and pyridines. Odour unit values, calculated from concentration and odour threshold data, indicate that the following compounds are major contributors to black-ripe table olive aroma: β-damascenone, nonanal, (E)-dec-2-enal, 3-methylbutanal, ethyl benzoate, octanal, 2-methoxyphenol, 2-methylbutanal and 2-methoxy-4-methylphenol. Imported olives contained a variety of fermentation derived volatiles that were not detected in domestic olives. Constituents such as ethyl 2-methylbutanoate, ethyl 3-methylbutanoate, 3-methylbutyl acetate, oct-1-en-3-one, ethyl hexanoate, (Z)-hex-3-enyl acetate, hexyl acetate, ethyl cyclohexanecarboxylate, benzyl acetate and 4-ethylphenol contributed to the odour of imported olives but were not detected in domestic olives.
商业黑熟期美国、西班牙、埃及和摩洛哥橄榄油的挥发性成分采用气相色谱和气相色谱-质谱联用技术(GC-MS)进行了分析。采用动态顶空采样法分离出各种醛类、醇类、酯类、酮类、酚类、萜类、异戊二烯类和吡啶类化合物。根据浓度和气味阈值数据计算出气味单位值,表明以下化合物是黑熟期橄榄油香气的主要贡献者:β-大马酮、壬醛、(E)-癸-2-烯醛、3-甲基丁醛、苯甲酸乙酯、辛醛、2-甲氧基苯酚、2-甲基丁醛和 2-甲氧基-4-甲基苯酚。进口橄榄中含有多种未在国产橄榄中检测到的发酵衍生挥发性物质。乙基 2-甲基丁酸酯、乙基 3-甲基丁酸酯、3-甲基丁酸丁酯、辛-1-烯-3-酮、己酸乙酯、(Z)-己-3-烯基乙酸酯、乙酸己酯、环己基乙酸乙酯、乙酸苄酯和 4-乙基苯酚等成分有助于进口橄榄的气味,但在国产橄榄中未被检测到。