叠氮吡啶1-氧化物光化学的比较研究

Comparative study of the photochemistry of the azidopyridine 1-oxides.

作者信息

Crabtree Kyle N, Hostetler Katherine J, Munsch Tamara E, Neuhaus Patrik, Lahti Paul M, Sander Wolfram, Poole James S

机构信息

Department of Chemistry, Ball State University, Muncie, Indiana 47306, USA.

出版信息

J Org Chem. 2008 May 2;73(9):3441-51. doi: 10.1021/jo8001936. Epub 2008 Apr 10.

DOI:10.1021/jo8001936

PMID:18399657

Abstract

The photochemistry of azidopyridine 1-oxides was studied using an array of glass and matrix isolation techniques. As with room temperature, the photochemistry of 4-azidopyridine 1-oxide is dominated by triplet nitrene chemistry. However, in the case of the 3-azide, matrix photolysis indicates the formation of diazabicyclo[4.1.0]hepta-2,4,6-triene N-oxide and diazacycloheptatetraene N-oxide intermediates as well as triplet nitrene.

摘要

利用一系列玻璃和基质隔离技术研究了叠氮吡啶1-氧化物的光化学。与室温情况一样，4-叠氮吡啶1-氧化物的光化学主要由三重态氮烯化学主导。然而，对于3-叠氮化物，基质光解表明形成了二氮杂双环[4.1.0]庚-2,4,6-三烯N-氧化物和二氮杂环庚四烯N-氧化物中间体以及三重态氮烯。