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环糊精[2]轮烷固态及溶液自组装中的分子纤维与分子线

Molecular fibers and wires in solid-state and solution self-assemblies of cyclodextrin [2]rotaxanes.

作者信息

Maniam Subashani, Cieslinski Marta M, Lincoln Stephen F, Onagi Hideki, Steel Peter J, Willis Anthony C, Easton Christopher J

机构信息

Research School of Chemistry, Australian National University, Canberra ACT 0200, Australia.

出版信息

Org Lett. 2008 May 15;10(10):1885-8. doi: 10.1021/ol8002145. Epub 2008 Apr 15.

DOI:10.1021/ol8002145
PMID:18410119
Abstract

Cyclodextrin [2]rotaxanes have been prepared by coupling dimethylanilines with dicarboxylic acids using DMT-MM, in aqueous solutions of alpha-cyclodextrin, and the example illustrated shows unusual fluorescence emission and other spectroscopic behavior characteristic of the formation of molecular wires in solution, similar to the fibers observed in the solid state.

摘要

通过使用DMT-MM,在α-环糊精水溶液中使二甲基苯胺与二羧酸偶联,制备了环糊精[2]轮烷,所举示例显示出异常的荧光发射以及溶液中分子线形成所特有的其他光谱行为,类似于在固态中观察到的纤维。

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Molecular fibers and wires in solid-state and solution self-assemblies of cyclodextrin [2]rotaxanes.环糊精[2]轮烷固态及溶液自组装中的分子纤维与分子线
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