Myers Timothy J
Exponent, Inc., 21 Strathmore Road, Natick, MA 01760, USA.
J Hazard Mater. 2008 Nov 15;159(1):72-80. doi: 10.1016/j.jhazmat.2008.02.106. Epub 2008 Mar 6.
Metal powders or dusts can represent significant dust explosion hazards in industry, due to their relatively low ignition energy and high explosivity. The hazard is well known in industries that produce or use aluminum powders, but is sometimes not recognized by facilities that produce aluminum dust as a byproduct of bulk aluminum processing. As demonstrated by the 2003 dust explosion at aluminum wheel manufacturer Hayes Lemmerz, facilities that process bulk metals are at risk due to dust generated during machining and finishing operations [U.S. Chemical Safety and Hazard Investigation Board, Investigation Report, Aluminum Dust Explosion Hayes Lemmerz International, Inc., Huntington, Indiana, Report No. 2004-01-I-IN, September 2005]. Previous studies have shown that aluminum dust explosions are more difficult to suppress with flame retardants or inerting agents than dust explosions fueled by other materials such as coal [A.G. Dastidar, P.R. Amyotte, J. Going, K. Chatrathi, Flammability limits of dust-minimum inerting concentrations, Proc. Saf. Progr., 18-1 (1999) 56-63]. In this paper, an inerting method is discussed to reduce the dust explosion hazard of residue created in an aluminum buffing operation as the residue is generated. This technique reduces the dust explosion hazard throughout the buffing process and within the dust collector systems making the process inherently safer. Dust explosion testing results are presented for process dusts produced during trials with varying amounts of flame retardant additives.
金属粉末或粉尘在工业中可能构成重大的粉尘爆炸危险,因为它们的点火能量相对较低且具有高爆炸性。这种危险在生产或使用铝粉的行业中是众所周知的,但有时生产铝粉尘作为块状铝加工副产品的设施却并未意识到这一点。正如2003年铝轮制造商海斯·莱默兹发生的粉尘爆炸所表明的那样,加工块状金属的设施因加工和精加工操作过程中产生的粉尘而面临风险[美国化学安全与危害调查委员会,调查报告,铝粉尘爆炸,海斯·莱默兹国际公司,印第安纳州亨廷顿,报告编号2004 - 01 - I - IN,2005年9月]。先前的研究表明,与由煤等其他材料引发的粉尘爆炸相比,铝粉尘爆炸更难用阻燃剂或惰性化剂来抑制[A.G. 达斯蒂达尔、P.R. 艾米奥特、J. 戈因、K. 查特拉蒂,粉尘的燃烧极限 - 最小惰化浓度,《安全进展》,18 - 1 (1999) 56 - 63]。本文讨论了一种惰性化方法,以在铝抛光操作产生残渣时降低其粉尘爆炸危险。该技术在整个抛光过程以及集尘器系统内降低了粉尘爆炸危险,使该过程本质上更安全。文中给出了在添加不同量阻燃添加剂的试验过程中产生的工艺粉尘的粉尘爆炸测试结果。