利用硫羰基对光化学γ-氢提取的手性记忆效应进行β-内酰胺的不对称合成。
Asymmetric synthesis of beta-lactams using chiral-memory effect on photochemical gamma-hydrogen abstraction by thiocarbonyl group.
作者信息
Sakamoto Masami, Kawanishi Hiroya, Mino Takashi, Fujita Tsutomu
机构信息
Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, Yayoi-cho, Inage-ku, Chiba, 263-8522, Japan.
出版信息
Chem Commun (Camb). 2008 May 14(18):2132-3. doi: 10.1039/b801524d. Epub 2008 Mar 26.
DOI:10.1039/b801524d
PMID:18438492
Abstract
Optically active beta-lactams were synthesized via photochemical intramolecular gamma-hydrogen abstraction reaction of thioimides involving a highly-controlled chiral-memory effect.
摘要
通过硫代酰亚胺的光化学分子内γ-氢提取反应，利用高度可控的手性记忆效应合成了光学活性β-内酰胺。
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