Sakamoto Masami, Kawanishi Hiroya, Mino Takashi, Kasashima Yoshio, Fujita Tsutomu
Department of Applied Chemistry and Biotechnology, Faculty of Engineering, Chiba University, Yayoi-cho, Inage-ku, Chiba, 263-8522, Japan.
Chem Commun (Camb). 2006 Nov 28(44):4608-10. doi: 10.1039/b608513j. Epub 2006 Sep 25.
Quaternary chiral carbons were effectively generated from tertiary chiral carbons via photochemical intramolecular beta-hydrogen abstraction reaction of thioimides involving the highly-controlled chiral-memory effect.
通过硫代酰亚胺的光化学分子内β-氢提取反应，利用高度可控的手性记忆效应，从叔手性碳有效地生成了季手性碳。
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