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中国黄海沿岸地区表层沉积物中有机污染物的多残留情况

Multi-residues of organic pollutants in surface sediments from littoral areas of the Yellow Sea, China.

作者信息

Liu WenXin, Chen JiangLin, Hu Jing, Ling Xi, Tao Shu

机构信息

Laboratory for Earth Surface Processes, College of Urban and Environmental Sciences, Peking University, Beijing 100871, PR China.

出版信息

Mar Pollut Bull. 2008 Jun;56(6):1091-103. doi: 10.1016/j.marpolbul.2008.03.021. Epub 2008 Apr 25.

Abstract

Concentrations of all studied organic pollutants, except for DDTs, were greatest at sites in Dalian Bay, where surface sediment concentrations of PHCs, PAHs, PCBs and DDTs exceeded the corresponding ERL values. The sum concentration of DDTs was greatest in Haizhou Bay exceeding the related ERM value. In terms of compositions of PAHs and PAEs, the predominant components were the MMW and HMW compounds, DBP and DEHP, respectively. The main degradation product of p,p'-DDT was p,p'-DDD at most sampling sites. The principal sources of PAHs and DDTs involved various pyrolytic processes (i.e., combustion of biomass and vehicle exhaust), and application of technical DDT (in the form of impurity or raw material), and a mixture of technical DDT and technical dicofol. Moreover, the coastal site with greatest potential ecological risk from total PAHs was located in Dalian Bay, while the littoral areas of Dalian Bay, two harbor cities (Yantai-Weihai), Jiaozhou Bay, and Haizhou Bay, had relatively high potential risk from DDTs, especially in Haizhou Bay.

摘要

除滴滴涕外,所有研究的有机污染物在大连湾各点位的浓度最高,大连湾表层沉积物中多环芳烃、多环芳烃、多氯联苯和滴滴涕的浓度超过了相应的效应范围低值(ERL)。滴滴涕的总浓度在海州湾最高,超过了相关的效应范围中值(ERM)值。就多环芳烃和邻苯二甲酸酯的组成而言,主要成分分别是中分子量和高分子量化合物、邻苯二甲酸二丁酯(DBP)和邻苯二甲酸二(2-乙基己基)酯(DEHP)。在大多数采样点位,p,p'-滴滴涕的主要降解产物是p,p'-滴滴滴。多环芳烃和滴滴涕的主要来源涉及各种热解过程(即生物质燃烧和汽车尾气排放)、工业用滴滴涕(以杂质或原料形式)以及工业用滴滴涕和三氯杀螨醇的混合物。此外,多环芳烃总潜在生态风险最大的沿海点位位于大连湾,而大连湾沿岸地区、两个港口城市(烟台-威海)、胶州湾和海州湾滴滴涕的潜在风险相对较高,尤其是在海州湾。

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