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胶州湾、桃子湾和四十里湾表层沉积物中有机氯农药的含量与分布

[Concentrations and distribution of organochlorine pesticides in the surface sediments of Jiaozhou Bay, Taozi Bay and Sishili Bay].

作者信息

Liu Yi-Kai, Zhong Guang-Cai, Tang Jian-Hui, Pan Xiao-Hui, Tian Chong-Guo, Chen Ying-Jun

机构信息

Key Laboratory of Coastal Zone Environmental Processes, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai 264003, China.

出版信息

Huan Jing Ke Xue. 2013 Jan;34(1):129-36.

Abstract

Forty-eight surface sediment samples collected from Jiaozhou Bay, Taozi Bay and Sishili Bay were analyzed for organochlorine pesticides (OCPs) by Gas Chromatography. Results showed that average concentrations of HCHs, HCB and DDTs in marine sediments were 0.33, 0.31 and 10.33 ng x g(-1) in Jiaozhou Bay and 0.26, 0.10 and 4.56 ng x g(-1) in Taozi Bay and Sishili Bay, respectively. Contamination status of OCPs was relatively higher in Jiaozhou Bay than in other inland coastal regions, especially for the levels of DDTs; however, OCPs concentrations were relatively low in Taozi Bay and Sishili Bay. The source of HCHs could be mainly attributed to the heavy historical application in agricultural areas and late transport to coastal region through surface runoff or riverine discharge, and DDTs were primarily originated from the use of technical DDTs. Fresh input of lindane and dicofol-type DDTs were found in several sites, such as Qingdao Port. High concentrations of DDTs in Jiaozhou Bay should arouse much attention.

摘要

采用气相色谱法对从胶州湾、桃子湾和四里湾采集的48个表层沉积物样本进行了有机氯农药(OCPs)分析。结果表明,胶州湾海洋沉积物中六氯环己烷(HCHs)、六氯苯(HCB)和滴滴涕(DDTs)的平均浓度分别为0.33、0.31和10.33 ng x g(-1),桃子湾和四里湾中三者的平均浓度分别为0.26、0.10和4.56 ng x g(-1)。胶州湾OCPs的污染状况相对高于其他内陆沿海地区,尤其是滴滴涕的含量;然而,桃子湾和四里湾的OCPs浓度相对较低。六氯环己烷的来源可能主要归因于农业地区过去大量使用以及后期通过地表径流或河流排放输送到沿海地区,而滴滴涕主要源于工业用滴滴涕的使用。在青岛港等几个地点发现了林丹和三氯杀螨醇型滴滴涕的新输入。胶州湾中高浓度的滴滴涕应引起高度关注。

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