Wang Li-Min, Liu Riping, Wang Wei Hua
State Key Laboratory of Metastable Materials Science and Technology and College of Materials Science and Engineering, Yanshan University, Qinhuangdao, Hebei 066004, People's Republic of China.
J Chem Phys. 2008 Apr 28;128(16):164503. doi: 10.1063/1.2904559.
Relaxation time dispersions in glass forming metallic liquids of diverse fragility characters were reviewed mainly based on mechanical relaxations. The compilation of the stretching exponents revealed the common nonexponential dynamic features among the metallic liquids. The time-temperature-superposition law of the relaxation profiles was identified with an average stretching exponent around 0.5 at low frequency regions near the glass transitions. No notable correlation of the stretching parameter with alloy composition was discerned. The construction of the frequency dependence of the stretching exponent across the whole range of liquid dynamics revealed a striking similarity of the nonexponential dynamics between metallic and fragile molecular liquids.
主要基于力学弛豫对具有不同脆性特征的玻璃形成金属液体中的弛豫时间色散进行了综述。拉伸指数的汇编揭示了金属液体之间常见的非指数动力学特征。在玻璃化转变附近的低频区域,弛豫曲线的时间-温度叠加定律被确定为平均拉伸指数约为0.5。未发现拉伸参数与合金成分之间有明显的相关性。在整个液体动力学范围内构建拉伸指数的频率依赖性,揭示了金属液体和脆性分子液体之间非指数动力学的显著相似性。