Guo Shaojun, Zhai Junfeng, Fang Youxing, Dong Shaojun, Wang Erkang
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, Jilin, China.
Chem Asian J. 2008 Jul 7;3(7):1156-62. doi: 10.1002/asia.200700422.
A high-efficiency nanoelectrocatalyst based on high-density Au/Pt hybrid nanoparticles supported on a silica nanosphere (Au-Pt/SiO2) has been prepared by a facile wet chemical method. Scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy are employed to characterize the obtained Au-Pt/SiO2. It was found that each hybrid nanosphere is composed of high-density small Au/Pt hybrid nanoparticles with rough surfaces. These small Au/Pt hybrid nanoparticles interconnect and form a porous nanostructure, which provides highly accessible activity sites, as required for high electrocatalytic activity. We suggest that the particular morphology of the Au-Pt/SiO2 may be the reason for the high catalytic activity. Thus, this hybrid nanomaterial may find a potential application in fuel cells.
通过一种简便的湿化学方法制备了一种基于负载在二氧化硅纳米球上的高密度金/铂混合纳米颗粒(Au-Pt/SiO₂)的高效纳米电催化剂。采用扫描电子显微镜、透射电子显微镜、能量色散X射线光谱和X射线光电子能谱对所得的Au-Pt/SiO₂进行表征。结果发现,每个混合纳米球由具有粗糙表面的高密度小金/铂混合纳米颗粒组成。这些小金/铂混合纳米颗粒相互连接并形成多孔纳米结构,这为高电催化活性所需的高可及活性位点提供了条件。我们认为Au-Pt/SiO₂的特殊形态可能是其高催化活性的原因。因此,这种混合纳米材料可能在燃料电池中找到潜在应用。