Liang Jinsheng, Zhu Dongbin, Meng Junping, Wang Lijuan, Li Fenping, Liu Zhiguo, Ding Yan, Liu Lihua, Liang Guangchuan
Institute of Power Source and Ecomaterials Science, Hebei University of Technology, Box 1055, Tianjin 300130, China.
J Nanosci Nanotechnol. 2008 Mar;8(3):1203-10.
Rare earth mineral composite materials were prepared using tourmaline and cerous nitrate as raw materials. Through characterization by scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, dynamic contact angle meter and tensiometer, and Fourier transform infrared spectroscopy, it was found that the composite materials had a better far infrared emitting performance than tourmaline, which depended on many factors such as material composition, microstructure, and surface free energy. Based on the results of the flue gas analyzer and the water boiling test, it was found that the rare earth mineral composite materials could accelerate the combustion of liquefied petroleum gas and diesel oil. The results showed that the addition of Ce led to the improvement of far infrared emitting performance of tourmaline due to the decrease of cell volume caused by the oxidation of more Fe2+ ions and the increase of surface free energy. The application of rare earth mineral composite materials to diesel oil led to a decrease in surface tension and flash point, and the fuel saving ratio could reach 4.5%. When applied to liquefied petroleum gas, the composite materials led to the enhanced combustion, improved fuel consumption by 6.8%, and decreased concentration of CO and O2 in exhaust gases by 59.7% and 16.2%, respectively; but the temperature inside the flue increased by 10.3%.
以电气石和硝酸铈为原料制备了稀土矿物复合材料。通过扫描电子显微镜、X射线衍射、X射线光电子能谱、动态接触角仪和张力仪以及傅里叶变换红外光谱进行表征,发现该复合材料具有比电气石更好的远红外发射性能,这取决于材料组成、微观结构和表面自由能等多种因素。基于烟气分析仪和水沸腾试验的结果,发现稀土矿物复合材料能够加速液化石油气和柴油的燃烧。结果表明,由于更多Fe2+离子氧化导致晶胞体积减小以及表面自由能增加,Ce的添加导致电气石远红外发射性能得到改善。稀土矿物复合材料应用于柴油导致表面张力和闪点降低,节油率可达4.5%。应用于液化石油气时,该复合材料导致燃烧增强,燃油消耗提高6.8%,废气中CO和O2浓度分别降低59.7%和16.2%;但烟道内温度升高了10.3%。