Wang Fei, Liang Jinsheng, Tang Qingguo, Li Liwei, Han Lijun
Institute of Power Source and Ecomaterials Science, Hebei University of Technology, Box 1055, Tianjin 300130, China.
J Nanosci Nanotechnol. 2010 Mar;10(3):2017-22. doi: 10.1166/jnn.2010.2116.
Sepiolite nanofibers were prepared by high-speed air current superfine technique, using natural sepiolite samples as raw materials. Through characterization by scanning electron microscope (SEM), X-ray diffraction (XRD), dynamic contact angle meter and tensiometer (DCAMT) and Fourier transform infrared spectroscope (FTIR), it was found that the defibered sepiolite nanofibers with an average diameter of about 100 nm and length greater than 9 microm had a better far infrared emitting performance than acid-purified sepiolite as the contrast sample, and the defibering treatment led to the improvement of far infrared emitting performance of sepiolite due to the increase of surface free energy, the increase of infrared active bond vibrations, and the decrease of cell volume caused by the distortion of structural channel.
以天然海泡石样品为原料,采用高速气流超细化技术制备海泡石纳米纤维。通过扫描电子显微镜(SEM)、X射线衍射(XRD)、动态接触角仪和张力仪(DCAMT)以及傅里叶变换红外光谱仪(FTIR)对其进行表征,发现平均直径约为100nm、长度大于9μm的解纤海泡石纳米纤维比作为对照样品的酸纯化海泡石具有更好的远红外发射性能,且解纤处理由于表面自由能增加、红外活性键振动增加以及结构通道畸变导致晶胞体积减小,从而使海泡石的远红外发射性能得到改善。