Nechaev A V, Mironov A F
Bioorg Khim. 2008 Mar-Apr;34(2):269-75. doi: 10.1134/s1068162008020167.
We treated with nucleophiles derivatives of chlorophyll a with additional six-membered cycles: delta-lactone at pyrrole D and anhydride at pyrrole C bearing a gamma-meso-bridge. In the first case, this led to the formation of substituted amides at the propionic acid residue and the introduction of hydroxy group at position 18 of the macrocycle, and, in the second case, to N-substituted cycloimides of chlorin p6. The English version of the paper: Russian Journal of Bioorganic Chemistry, 2008, vol. 34, no. 2; see also http://www.maik.ru
我们用带有额外六元环的叶绿素a的亲核试剂衍生物进行处理:吡咯D处的δ-内酯和带有γ-中位桥的吡咯C处的酸酐。在第一种情况下,这导致在丙酸残基处形成取代酰胺,并在大环的18位引入羟基;在第二种情况下,导致形成二氢卟吩p6的N-取代环酰亚胺。该论文的英文版本:《俄罗斯生物有机化学杂志》,2008年,第34卷,第2期;另见http://www.maik.ru