配体与金属比例控制的纳米多孔金属有机框架的组装

Ligand-to-metal ratio controlled assembly of nanoporous metal-organic frameworks.

作者信息

Lin Jian-Guo, Xu Yan-Yan, Qiu Ling, Zang Shuang-Quan, Lu Chang-Sheng, Duan Chun-Ying, Li Yi-Zhi, Gao Song, Meng Qing-Jin

机构信息

Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China.

出版信息

Chem Commun (Camb). 2008 Jun 21(23):2659-61. doi: 10.1039/b802992j. Epub 2008 May 8.

DOI:10.1039/b802992j

PMID:18535699

Abstract

Two bilayered metal-organic frameworks with nanoporous channels were synthesized at different ligand-to-metal ratios, which demonstrated an interesting crystal-to-crystal transformation property and a special fluorescent response to the different guest molecules included.

摘要

合成了两种具有纳米孔道的双层金属有机框架，其配体与金属比例不同，展现出有趣的晶型到晶型转变特性以及对所含不同客体分子的特殊荧光响应。