Wang Jin-Min, Li Dong-Feng, Wang Fang, Liu Ao, Li Min
College of Biotechnology, Changchun University of Technology, Changchun 130012, China.
Guang Pu Xue Yu Guang Pu Fen Xi. 2008 Mar;28(3):629-32.
Pyrazoline derivatives have been investigated in many aspects due to their blue light emission with high quantum yield, ready accessibility, and easily being used as carrier transporting as well as emitting materials. According to Schellhammer theory of the relation between chemical structure and fluorescent quality, we designed some new fluorescent compounds with the benzothiazoyl group in the 1-pyrazoline, the derivatives of phenyl in the 3-pyrazoline and the furan in the 5-pyrazoline, and they possess fluorescent nature. In addition, the results of our research have shown that the benzothiazoyl derivatives can also be used for electroluminescence devices. Several benzothiazoyl pyrazoline compounds were synthesized, and their structures were confirmed by IR, 1H NMR, fluorescence spectrum and elementary analysis. The fluorescence spectra showed that these compounds have good fluorescence. The fluorescence emission wavelengths are about 440-460 nm, and the fluorescence intensity is related to the substituent of the compounds.
由于吡唑啉衍生物具有高量子产率的蓝光发射、易于获得且易于用作载流子传输以及发光材料等特性,因此已在许多方面对其进行了研究。根据Schellhammer关于化学结构与荧光性质之间关系的理论,我们设计了一些新的荧光化合物,它们在1-吡唑啉中带有苯并噻唑基,在3-吡唑啉中带有苯基衍生物,在5-吡唑啉中带有呋喃,并且它们具有荧光性质。此外,我们的研究结果表明,苯并噻唑基衍生物也可用于电致发光器件。合成了几种苯并噻唑基吡唑啉化合物,并通过红外光谱、1H核磁共振、荧光光谱和元素分析对其结构进行了确证。荧光光谱表明这些化合物具有良好的荧光。荧光发射波长约为440 - 460 nm,并且荧光强度与化合物的取代基有关。