Xian Yuan-fang, Li Dong-feng, Li Hai-dong, Yu Bao-hui
School of Chemical Engineering, Changchun University of Technology, Changchun 130012, China.
Guang Pu Xue Yu Guang Pu Fen Xi. 2005 Mar;25(3):391-4.
Benzothiazole compounds with byrazoline group or benximidazole group are new fluorescent compounds. The fluorescent compounds have been used in many fields, but their development has beeo slow. According to Schellhammer theory on the relation between chemical structure and fluorescent quality, the authors designed now fluorescent compounds with benximidazole group or the byrazoline group in the 1-benzothiazole and with biphenyl in the 3,5-benzothiazole, and their possess fluorescent nature. Two new benximidazole and benzothiazole fluorescent compounds were synthesized. All these compounds were characterized by elemental analysis and infrared spectroscopy. The excitation wavelength of the two compounds is about 441-446 nm. The fluorescence spectra show that the compounds have good blue and green fluorescence. The characteristic peaks of t he absorption spectra of these compounds werefound by IR spectral analysis, which can be used to deduce the structures of chemical compounds.
含有吡唑啉基团或苯并咪唑基团的苯并噻唑化合物是新型荧光化合物。这些荧光化合物已在许多领域得到应用,但其发展一直较为缓慢。根据舍尔哈默关于化学结构与荧光性质关系的理论,作者设计了在1-苯并噻唑中带有苯并咪唑基团或吡唑啉基团且在3,5-苯并噻唑中带有联苯的新型荧光化合物,它们具有荧光性质。合成了两种新型苯并咪唑和苯并噻唑荧光化合物。所有这些化合物均通过元素分析和红外光谱进行了表征。这两种化合物的激发波长约为441 - 446 nm。荧光光谱表明这些化合物具有良好的蓝色和绿色荧光。通过红外光谱分析找到了这些化合物吸收光谱的特征峰,可用于推导化合物的结构。