López-López Modesto T, Gómez-Ramírez Ana, Durán Juan D G, González-Caballero Fernando
Department of Applied Physics, Faculty of Sciences, University of Granada, Avda Fuentenueva s/n, 18071 Granada, Spain.
Langmuir. 2008 Jul 15;24(14):7076-84. doi: 10.1021/la703519p. Epub 2008 Jun 10.
Suspensions of micrometer-sized iron particles (10 vol %) dispersed in kerosene and stabilized by addition of organoclay particles were prepared. The magnetization curves of these suspensions were measured, and their sedimentation and redispersion behaviors were analyzed as a function of clay concentration by means of optical and rheological methods. Furthermore, their magnetorheological properties were investigated using a controlled rate magnetorheometer and the effect of clay concentration on these properties was also analyzed. These experiments showed that the addition of clay slows down iron particle settling and eases the redispersion of the iron-based suspensions without masking their magnetorheological properties. Two mechanisms were found to be involved in this behavior: (i) the formation of a clay gel network and (ii) the presence of heterogeneous iron-clay adhesion.
制备了微米级铁颗粒(10体积%)分散在煤油中并通过添加有机粘土颗粒稳定的悬浮液。测量了这些悬浮液的磁化曲线,并通过光学和流变学方法分析了它们的沉降和再分散行为与粘土浓度的关系。此外,使用可控速率磁流变仪研究了它们的磁流变性能,并分析了粘土浓度对这些性能的影响。这些实验表明,添加粘土可减缓铁颗粒沉降,并使铁基悬浮液的再分散变得容易,同时不会掩盖其磁流变性能。发现这种行为涉及两种机制:(i)粘土凝胶网络的形成和(ii)铁-粘土异质粘附的存在。