二维 Kagomé 晶格的超分子工程：合成、结构与磁性

Supramolecular engineering of a 2D Kagomé lattice: synthesis, structures, and magnetic properties.

作者信息

Yue Yan-Feng, Liang Jue, Gao En-Qing, Fang Chen-Jie, Yan Zheng-Guang, Yan Chun-Hua

机构信息

Beijing National Laboratory for Molecular Sciences, Peking University, Beijing 100871, China.

出版信息

Inorg Chem. 2008 Jul 21;47(14):6115-7. doi: 10.1021/ic800497n. Epub 2008 Jun 14.

DOI:10.1021/ic800497n

PMID:18553910

Abstract

Two 2D Mn (II) complexes, [Mn3(TzDC)2(phen)3] x 2 H2O (1; H3TzDC = 1,2,3-triazole-4,5-dicarboxylic acid, phen = 1,10-phenanthroline) and [Mn3(TzDC)2(bipy)3] x 4 H2O (2; bipy = 2,2'-bipyridine), were synthesized by hydrothermal reactions and characterized magnetically, and complex 1 was the first example of the chiral complex with a Kagomé lattice connectivity obtained through spontaneous resolution.

摘要

通过水热反应合成了两种二维锰（II）配合物，[Mn3(TzDC)2(phen)3]·2H2O（1；H3TzDC = 1,2,3-三唑-4,5-二羧酸，phen = 1,10-菲咯啉）和[Mn3(TzDC)2(bipy)3]·4H2O（2；bipy = 2,2'-联吡啶），并对其进行了磁性表征，配合物1是通过自发拆分得到的具有 Kagomé 晶格连通性的手性配合物的首个实例。