Department of Chemistry, Capital Normal University, No. 105, Xisanhuan Beilu, Haidian District, Beijing, 100048, China.
Molecules. 2010 May 12;15(5):3478-506. doi: 10.3390/molecules15053478.
This paper provides a brief review of recent progress in the field of metal coordination polymers assembled from azole-containing carboxylic acids and gives a diagrammatic summary of the diversity of topological structures in the resulting infinite metal-organic coordination networks (MOCNs). Azole-containing carboxylic acids are a favorable kind of multifunctional ligand to construct various metal complexes with isolated complexes and one, two and three dimensional structures, whose isolated complexes are not the focus of this review. An insight into the topology patterns of the infinite coordination polymers is provided. Analyzed topologies are compared with documented topologies and catalogued by the nature of nodes and connectivity pattern. New topologies which are not available from current topology databases are described and demonstrated graphically.
本文简要综述了近年来含唑羧酸构筑的金属配位聚合物领域的研究进展，并用示意图总结了所得无限金属-有机配位网络（MOCN）的拓扑结构多样性。含唑羧酸是一种理想的多功能配体，可构建具有孤立配合物和一、二、三维结构的各种金属配合物，其孤立配合物不是本文综述的重点。本文对无限配位聚合物的拓扑模式进行了深入探讨。分析的拓扑结构与已记录的拓扑结构进行了比较，并根据节点的性质和连接模式进行了分类。对当前拓扑数据库中尚未收录的新拓扑结构进行了描述和图形展示。
