Alzuet G, Ferrer S, Borrás J
Departamento de Química Inorgánica, Facultad de Farmacia, Universidad de Valencia, Spain.
J Inorg Biochem. 1991 May 1;42(2):79-86. doi: 10.1016/0162-0134(91)80034-f.
Complexes of Co(II), Ni(II), and Cu(II) with dideprotonated Acm are synthesized and characterized. Acm acts as bidentate ligand through the N-sulfonamido atom and the N-thiadiazole atom except for K6CoAcm4.6H2O in which Acm behaves as monodentate through the N-sulfonamido atom.
合成并表征了钴(II)、镍(II)和铜(II)与去质子化的Acm形成的配合物。除了K6CoAcm4·6H2O中Acm通过N-磺酰胺基原子以单齿形式存在外,Acm通过N-磺酰胺基原子和N-噻二唑原子作为双齿配体。