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用于二氧化碳吸收的2-氨基-2-甲基-1-丙醇的再生

Regeneration of 2-amino-2-methyl-1-propanol used for carbon dioxide absorption.

作者信息

Zhang Pei, Shi Yao, Wei Jianwen, Zhao Wei, Ye Qing

机构信息

Department of Environmental Science, Zhejiang University, Hangzhou 310028, China.

出版信息

J Environ Sci (China). 2008;20(1):39-44. doi: 10.1016/s1001-0742(08)60005-4.

Abstract

To improve the efficiency of the carbon dioxide cycling process and to reduce the regeneration energy consumption, a sterically hindered amine of 2-amino-2-methyl-1-propranol (AMP) was investigated to determine its regeneration behavior as a CO2 absorbent. The CO2 absorption and amine regeneration characteristics were experimentally examined under various operating conditions. The regeneration efficiency increased from 86.2% to 98.3% during the temperature range of 358 to 403 K. The most suitable regeneration temperature for AMP was 383 K, in this experiment condition, and the regeneration efficiency of absorption/regenerationruns descended from 98.3% to 94.0%. A number of heat-stable salts (HSS) could cause a reduction in CO2 absorption capacity and regeneration efficiency. The results indicated that aqueous AMP was easier to regenerate with less loss of absorption capacity than other amines, such as, monoethanolamine (MEA), diethanolamine (DEA), diethylenetriamine (DETA), and N-methyldiethanolamine (MDEA).

摘要

为提高二氧化碳循环过程的效率并降低再生能耗,对空间位阻胺2-氨基-2-甲基-1-丙醇(AMP)进行了研究,以确定其作为二氧化碳吸收剂的再生行为。在各种操作条件下,对二氧化碳吸收和胺再生特性进行了实验研究。在358至403K的温度范围内,再生效率从86.2%提高到98.3%。在本实验条件下,AMP最合适的再生温度为383K,吸收/再生运行的再生效率从98.3%降至94.0%。多种热稳定盐(HSS)会导致二氧化碳吸收容量和再生效率降低。结果表明,与单乙醇胺(MEA)、二乙醇胺(DEA)、二乙烯三胺(DETA)和N-甲基二乙醇胺(MDEA)等其他胺相比,AMP水溶液更容易再生,吸收容量损失更小。

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