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Charge separation by ditopic complexation in the solid state: molecular structure of {Ph2(I)SnCH2Sn(Ph)(I)CH2-[16]-crown-5}.NaF.CH3OH.

作者信息

Reeske Gregor, Schürmann Markus, Jurkschat Klaus

机构信息

Lehrstuhl für Anorganische Chemie II, Technische Universität Dortmund, 44221 Dortmund.

出版信息

Dalton Trans. 2008 Jul 14(26):3398-400. doi: 10.1039/b803552k. Epub 2008 Mar 18.

DOI:10.1039/b803552k
PMID:18580975
Abstract

An intramolecular O-H-F hydrogen bridge involving a methanol molecule provides communication between the strongly separated sodium cation and fluoride anion in sodium fluoride that is, for the first time and despite its high lattice energy, ditopically complexed by an organotin-substituted crown ether.

摘要

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