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[臭氧浓度升高对银杏和油松挥发性有机化合物排放的影响]

[Effects of elevated O3 on the volatile organic compounds emit from Ginkgo biloba and Pinus tabulaeformis].

作者信息

Li De-wen, Shi Yi, He Xing-yuan

机构信息

Key Laboratory of Terrestrial Ecological Process, Institute of Applied Ecology, Chinese Academy of Sciences, Shenyang 110016, China.

出版信息

Huan Jing Ke Xue. 2008 Feb;29(2):300-4.

Abstract

To study the impact of elevated tropospheric O3 concentrations on BVOCs emissions by Pinus tabulaeformis and Ginkgo biloba in urban area, the trees were exposed in open-top chambers. Two ozone treatments were established: ambient air (approximately 30 nmol x mol(-1) ) (CK) and elevated O3 concentrations (80 nmol x mol(-1) ) (O3 ). Elevated O3 concentrations significantly induced isoprene to emit for Pinus tabulaeformis and Ginkgo biloba (p < 0.05), and delta3-carene for Ginkgo biloba (p < 0.05). The emission rates were increased to 1.96, 9.71 and 0.09 microg/(g x h) (-1), respectively. There were no significant differences between ozone fumigation treatments for the other monoterpenes. At the same time, the relative abundances of the monoterpenes and isoprene were to be different between tree species and effect by O3 exposure. In CK chambers, the dominate BVOCs emitted by Ginkgo biloba was isoprene, and a-pinene for Pinus tabulaeformis. In the elevated O3 chambers, the isoprene accounted for 64.73% of Pinus tabulaeformis BVOCs. To sum up, the BVOCs emitting patterns were influenced by elevated O3 significantly.

摘要

为研究城市地区对流层臭氧浓度升高对油松和银杏生物挥发性有机化合物(BVOCs)排放的影响,将树木置于开顶式气室中。设置了两种臭氧处理:环境空气(约30 nmol·mol⁻¹)(CK)和升高的臭氧浓度(80 nmol·mol⁻¹)(O3)。升高的臭氧浓度显著诱导油松和银杏排放异戊二烯(p < 0.05),以及银杏排放δ-3-蒈烯(p < 0.05)。排放速率分别增加到1.96、9.71和0.09 μg/(g·h)⁻¹。其他单萜类化合物在臭氧熏蒸处理之间没有显著差异。同时,单萜类化合物和异戊二烯的相对丰度在不同树种之间存在差异,并且受臭氧暴露的影响。在CK气室中,银杏排放的主要BVOCs是异戊二烯,油松排放的是α-蒎烯。在臭氧浓度升高的气室中,异戊二烯占油松BVOCs的64.73%。综上所述,升高的臭氧显著影响BVOCs的排放模式。

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