Sain Anirban
Physics Department, Indian Institute of Technology-Bombay, Powai, Mumbai, India.
Phys Rev E Stat Nonlin Soft Matter Phys. 2008 Jun;77(6 Pt 1):061919. doi: 10.1103/PhysRevE.77.061919. Epub 2008 Jun 23.
We compute the effect of hydrodynamic interaction and stretching on the fluctuation properties of a polymer, with its end points held fixed. Computing the preaveraged hydrodynamic tensor exactly for this geometry, we study both flexible and semiflexible polymer chains, such as Zimm, freely jointed chain, and wormlike chain (WLC) models. We compare the spectra of relaxation-time scales for the effective normal modes of these models. The spectra differ across models with respect to the degree of stretch, but their power-law scaling with low mode numbers turns out to be the same. The characteristics of the transverse modes of WLC agree very well with the experimental data on DNA. The crossover scaling function for (1/r), the inverse of the distance along the polymer contour, yields a modified formula for the size of a "Pincus blob," appropriate for the fixed-end boundary condition.
我们计算了流体动力学相互作用和拉伸对聚合物涨落特性的影响,聚合物的端点保持固定。通过精确计算这种几何结构的预平均流体动力学张量,我们研究了柔性和半柔性聚合物链,如齐默尔模型、自由连接链模型和蠕虫状链(WLC)模型。我们比较了这些模型有效正常模式的弛豫时间尺度谱。这些谱在不同模型中随拉伸程度而不同,但它们在低模式数下的幂律标度结果是相同的。WLC横向模式的特征与DNA的实验数据非常吻合。对于沿聚合物轮廓的距离的倒数(1/r)的交叉标度函数,给出了一个适用于固定端边界条件的“平卡斯微区”尺寸的修正公式。