Block copolymer-like self-assembly of fluorocarbon end-functionalized polystyrene and polybutylmethacrylate.

作者信息

Shen Jingguo, Hogen-Esch Thieo

机构信息

Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, Los Angeles, California 90089, USA.

出版信息

J Am Chem Soc. 2008 Aug 20;130(33):10866-7. doi: 10.1021/ja803375a. Epub 2008 Jul 23.

DOI:10.1021/ja803375a

PMID:18646751

Abstract

We demonstrate the self-assembly through fluorophilic interactions of a blend of perfluorocarbon (RF) end-functionalized polystyrene and the corresponding RF-polybutylmethacrylate into optically transparent materials that retain domain characteristics typical of the component polymers but show well-defined lamellar nanostructured morphologies that qualitatively resemble that of the corresponding block copolymers.

摘要