Corbet Matthieu, Ferjancić Zorana, Quiclet-Sire Béatrice, Zard Samir Z
Laboratoire de Synthèse Organique, CNRS UMR 7652, Département de Chimie, Ecole Polytechnique, 91128 Palaiseau, France.
Org Lett. 2008 Aug 21;10(16):3579-82. doi: 10.1021/ol801348u. Epub 2008 Jul 23.
Xanthates have been readily converted into o-chlorophenyl thioethers using a one-step procedure conducted under radical conditions. In some selected cases, these aryl thioethers were successfully oxidized to the corresponding sulfoxides and sulfenic acid elimination afforded the corresponding vinylsilanes.
使用在自由基条件下进行的一步法,黄原酸盐已很容易地转化为邻氯苯基硫醚。在一些选定的情况下,这些芳基硫醚成功地被氧化为相应的亚砜,并且亚磺酸消除反应得到了相应的乙烯基硅烷。