Asymmetric oxidative cation/olefin cyclization of polyenes: evidence for reversible cascade cyclization.
作者信息
Mullen Charles A, Campbell Alison N, Gagné Michel R
机构信息
Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, NC 27599-3290, USA.
出版信息
Angew Chem Int Ed Engl. 2008;47(32):6011-4. doi: 10.1002/anie.200801423.
Abstract
摘要
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Reversibility effects on the stereoselectivity of Pt(II)-mediated cascade poly-ene cyclizations.关于铂（II）介导的级联多烯环化反应立体选择性的可逆性影响。
J Am Chem Soc. 2008 Jan 16;130(2):592-9. doi: 10.1021/ja075518i. Epub 2007 Dec 21.
2
Gold(I)-catalyzed dynamic kinetic enantioselective intramolecular hydroamination of allenes.金（I）催化的丙二烯分子内动态动力学对映选择性氢胺化反应。
J Am Chem Soc. 2007 Nov 21;129(46):14148-9. doi: 10.1021/ja0760731. Epub 2007 Oct 30.
3
Regioselective oxidative cation-olefin cyclization of poly-enes: catalyst turnover via hydride abstraction.多烯的区域选择性氧化阳离子-烯烃环化反应：通过氢化物提取实现催化剂周转
J Am Chem Soc. 2007 Oct 3;129(39):11880-1. doi: 10.1021/ja073573l. Epub 2007 Sep 13.
4
Electrophilic activation of alkenes by platinum(II): so much more than a slow version of palladium(II).铂（II）对烯烃的亲电活化：远不止是钯（II）的慢速版本。
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Gold(I)-catalyzed intramolecular enantioselective hydroarylation of allenes with indoles.金（I）催化的丙二烯与吲哚的分子内对映选择性氢芳基化反应。
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Catalytic carbophilic activation: catalysis by platinum and gold pi acids.催化亲碳活化：铂和金π酸催化作用
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Kinetic and computational analysis of the palladium(II)-catalyzed asymmetric allylic trichloroacetimidate rearrangement: development of a model for enantioselectivity.钯（II）催化的不对称烯丙基三氯乙酰亚胺酯重排反应的动力学与计算分析：对映选择性模型的建立
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Nature. 2007 Feb 22;445(7130):900-3. doi: 10.1038/nature05553.
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Gold(I)-catalyzed enantioselective intramolecular hydroamination of allenes.金（I）催化的丙二烯对映选择性分子内氢胺化反应。
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