Cagnon Benoît, Py Xavier, Guillot André, Stoeckli Fritz, Chambat Gérard
Laboratoire de Génie des Procédés pour l'Environnement, l'Energie, et la Santé GP2ES-EA21, Institut Universitaire de Technologie, Université d'Orléans, Rue d'Issoudun, Orléans Cedex 2, France.
Bioresour Technol. 2009 Jan;100(1):292-8. doi: 10.1016/j.biortech.2008.06.009. Epub 2008 Jul 22.
In this study, contributions of hemicellulose, cellulose and lignin to the mass and the porous properties of chars and activated carbons from various lignocellulosic materials were studied. A predictive calculation was established using the experimental results obtained for the three components separately to evaluate the carbonization and activation yields and their respective contributions to the chars and to the subsequent activated carbons of various precursors in term of weight fraction. These equations were validated. The results showed that lignin can be considering as being the major contributor of all chars and activated carbons. Besides, the evolution of the mean pore size versus the specific porous volume showed that each component contributes to the porosity of chars and activated carbons whatever is its weight contribution.
在本研究中,研究了半纤维素、纤维素和木质素对各种木质纤维素材料制成的炭和活性炭的质量及多孔性能的贡献。利用分别针对这三种组分获得的实验结果建立了一个预测计算模型,以评估碳化产率和活化产率,以及它们在重量分数方面对各种前驱体制备的炭及后续活性炭的各自贡献。这些方程得到了验证。结果表明,木质素可被视为所有炭和活性炭的主要贡献者。此外,平均孔径与比孔容的关系演变表明,无论各组分的重量贡献如何,它们都对炭和活性炭的孔隙率有贡献。