Tian Jia-Yu, Liang Heng, Li Xing, You Shi-jie, Tian Sen, Li Gui-bai
School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin 150090, China.
Water Res. 2008 Aug;42(14):3910-20. doi: 10.1016/j.watres.2008.05.025. Epub 2008 Jun 24.
In this paper, a novel submerged ultrafiltration (UF) membrane coagulation bioreactor (MCBR) process was evaluated for drinking water treatment at a hydraulic retention time (HRT) as short as 0.5h. The MCBR performed well not only in the elimination of particulates and microorganisms, but also in almost complete nitrification and phosphate removal. As compared to membrane bioreactor (MBR), MCBR achieved much higher removal efficiencies of organic matter in terms of total organic carbon (TOC), permanganate index (COD(Mn)), dissolved organic carbon (DOC) and UV absorbance at 254nm (UV(254)), as well as corresponding trihalomethanes formation potential (THMFP) and haloacetic acids formation potential (HAAFP), due to polyaluminium chloride (PACl) coagulation in the bioreactor. However, the reduction of biodegradable dissolved organic carbon (BDOC) and assimilable organic carbon (AOC) by MCBR was only 8.2% and 10.1% higher than that by MBR, indicating that biodegradable organic matter (BOM) was mainly removed through biodegradation. On the other hand, the trans-membrane pressure (TMP) of MCBR developed much lower than that of MBR, which implies that coagulation in the bioreactor could mitigate membrane fouling. It was also identified that the removal of organic matter was accomplished through the combination of three unit effects: rejection by UF, biodegradation by microorganism and coagulation by PACl. During filtration operation, a fouling layer was formed on the membranes surface of both MCBR and MBR, which functioned as a second membrane for further separating organic matter.
本文评估了一种新型的淹没式超滤(UF)膜混凝生物反应器(MCBR)工艺在水力停留时间(HRT)低至0.5小时的情况下用于饮用水处理的效果。MCBR不仅在去除颗粒物和微生物方面表现良好,而且在几乎完全硝化和除磷方面也表现出色。与膜生物反应器(MBR)相比,由于生物反应器中聚合氯化铝(PACl)的混凝作用,MCBR在总有机碳(TOC)、高锰酸盐指数(COD(Mn))、溶解有机碳(DOC)和254nm处的紫外线吸光度(UV(254))等有机物去除效率方面,以及相应的三卤甲烷生成势(THMFP)和卤乙酸生成势(HAAFP)方面都取得了更高的去除效率。然而,MCBR对可生物降解溶解有机碳(BDOC)和可同化有机碳(AOC)的去除率仅比MBR高8.2%和10.1%,这表明可生物降解有机物(BOM)主要通过生物降解去除。另一方面,MCBR的跨膜压力(TMP)增长远低于MBR,这意味着生物反应器中的混凝作用可以减轻膜污染。还发现有机物的去除是通过三种单元作用的组合实现的:超滤截留、微生物生物降解和PACl混凝。在过滤操作过程中,MCBR和MBR的膜表面都形成了一个污染层,该污染层起到了进一步分离有机物的第二道膜的作用。