锰催化的过氧化氢不对称顺式二羟基化反应
Manganese catalysed asymmetric cis-dihydroxylation with H2O2.
作者信息
de Boer Johannes W, Browne Wesley R, Harutyunyan Syuzanna R, Bini Laura, Tiemersma-Wegman Theodora D, Alsters Paul L, Hage Ronald, Feringa Ben L
机构信息
Stratingh Institute for Chemistry, Faculty of Mathemathics and Natural Sciences, University of Groningen, Nijenborgh 4, Groningen 9747 AG, The Netherlands.
出版信息
Chem Commun (Camb). 2008 Aug 28(32):3747-9. doi: 10.1039/b808355j. Epub 2008 Jul 17.
DOI:10.1039/b808355j
PMID:18685764
Abstract
High turnover enantioselective alkene cis-dihydroxylation is achieved with H(2)O(2) catalysed by manganese based complexes containing chiral carboxylato ligands.
摘要
通过含有手性羧基配体的锰基配合物催化H₂O₂，实现了高周转对映选择性烯烃顺式二羟基化反应。
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