聚恶唑啉胶束在离子液体和水之间的可控热可逆转移
Controlled thermoreversible transfer of poly(oxazoline) micelles between an ionic liquid and water.
作者信息
Guerrero-Sanchez Carlos, Gohy Jean-François, D'Haese Cecile, Thijs Hanneke, Hoogenboom Richard, Schubert Ulrich S
机构信息
Laboratory of Macromolecular Chemistry and Nanoscience, Eindhoven University of Technology, PO Box 513, 5600 MB Eindhoven, The Netherlands.
出版信息
Chem Commun (Camb). 2008 Jun 28(24):2753-5. doi: 10.1039/b804179b. Epub 2008 May 20.
Poly(2-nonyl-2-oxazoline-block-2-ethyl-2-oxazoline) block copolymer micelles were investigated as an alternative system to the approach proposed by He and Lodge (Y. He and T. P. Lodge, J. Am. Chem. Soc., 2006, 128, 12666) for the thermoreversible transfer of micelles between a hydrophobic ionic liquid phase and an aqueous phase; this work describes the possibility of thermally triggering and controlling this process.
研究了聚（2-壬基-2-恶唑啉-嵌段-2-乙基-2-恶唑啉）嵌段共聚物胶束，将其作为一种替代体系，用于He和Lodge提出的方法（Y. He和T. P. Lodge，《美国化学会志》，2006年，128卷，12666页），以实现胶束在疏水离子液体相和水相之间的热可逆转移；这项工作描述了热触发和控制该过程的可能性。
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