关于氘在涉及氢原子转移的自由基反应中作为碳氢键“保护基团”有效性的研究。
Investigations into the effectiveness of deuterium as a "protecting group" for C-H bonds in radical reactions involving hydrogen atom transfer.
作者信息
Wood Mark E, Bissiriou Sabine, Lowe Christopher, Windeatt Kim M
机构信息
School of Biosciences (originally Department of Chemistry), University of Exeter, Geoffrey Pope Building, Stocker Road, Exeter, EX4 4QD, UK.
出版信息
Org Biomol Chem. 2008 Sep 7;6(17):3048-51. doi: 10.1039/b810018g. Epub 2008 Jul 22.
DOI:10.1039/b810018g
PMID:18698461
Abstract
Competition experiments have been carried out to determine the extent to which deuterium can be used as a protecting group for carbon-hydrogen bonds in radical-based intramolecular hydrogen atom transfer processes.
摘要
已经进行了竞争实验，以确定在基于自由基的分子内氢原子转移过程中，氘可以在多大程度上用作碳氢键的保护基团。
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