Angelici Robert J, Lazar Mihaela
Ames Laboratory (U.S. DOE) and Department of Chemistry, Iowa State University, Ames, Iowa 50011-3111, USA.
Inorg Chem. 2008 Oct 20;47(20):9155-65. doi: 10.1021/ic800513t. Epub 2008 Aug 26.
Knowledge of the coordination chemistry and reactivity of isocyanide ligands in transition-metal complexes forms the basis for understanding the adsorption and reactions of isocyanides on metal surfaces. In this overview, we explore reactions (often catalytic) of isocyanides adsorbed on metal surfaces that reflect their patterns of reactivity in metal complexes. We also examine applications of isocyanide adsorption to the stabilization of metal nanoparticles, the functionalization of metal electrodes, and the creation of conducting organic-metal junctions in molecule-scale electronic devices.
了解过渡金属配合物中异腈配体的配位化学和反应活性是理解异腈在金属表面吸附和反应的基础。在本综述中，我们探讨了吸附在金属表面的异腈的反应（通常是催化反应），这些反应反映了它们在金属配合物中的反应活性模式。我们还研究了异腈吸附在金属纳米颗粒稳定化、金属电极功能化以及分子尺度电子器件中导电有机-金属结创建方面的应用。
