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Transport of metal salts by zwitterionic ligands; simple but highly efficient salicylaldoxime extractants.

作者信息

Forgan Ross S, Davidson James E, Galbraith Stuart G, Henderson David K, Parsons Simon, Tasker Peter A, White Fraser J

机构信息

School of Chemistry, University of Edinburgh, Edinburgh, UK EH9 3JJ.

出版信息

Chem Commun (Camb). 2008 Sep 14(34):4049-51. doi: 10.1039/b808696f. Epub 2008 Jul 29.

DOI:10.1039/b808696f
PMID:18758622
Abstract

Attaching dialkylaminomethyl arms to commercial phenolic oxime copper extractants yields reagents which transport base metal salts very efficiently by forming neutral 1:1 or 1:2 complexes with zwitterionic forms of the ligands.

摘要

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The zwitterion (23'E)-(23R,25S)-23-[1-(oxidoiminio)eth-yl]-5β-spiro-stan-3β-yl acetate.
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Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 31;65(Pt 11):o2954-5. doi: 10.1107/S1600536809044651.