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双酚A在厌氧污泥上的吸附行为

[Sorption behavior of bisphenol A on anaerobic sludge].

作者信息

Zhao Jun-ming, Li Yong-mei, Zhou Qi, Zhang Chao-jie, Zeng Qing-ling

机构信息

State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Shanghai 200092, China.

出版信息

Huan Jing Ke Xue. 2008 Jun;29(6):1681-6.

Abstract

Batch experiments were conducted to investigate the sorption behavior of bisphenol A (BPA) with low concentration on anaerobic sludge. The autoclaved inactivated sludge was used to minimize the influence of degradation of activated sludge. The results showed that the sorption of BPA on anaerobic sludge was a quick process. Anaerobic sludge had achieved 89.1% of the maximum sorption capacity at 15 min. The sorption isotherms of BPA were fitted well by Freundlich and linear sorption models. The sorption coefficients normalized by organic carbon contents were in the range of 665-878 at 10-30 degrees C. MLSS had significant effect on the sorption behavior. With the increase in MLSS, the sorption removal efficiency increased. Through the determination of thermodynamics parameters of BPA, it can be concluded that the sorption of BPA on the anaerobic sludge was mainly a physical process and partitioning between the water and sludge phases played a dominant role. Desorption tests showed that BPA sorption on anaerobic sludge was partially reversible.

摘要

进行了批次实验以研究低浓度双酚A(BPA)在厌氧污泥上的吸附行为。使用经高压灭菌的灭活污泥以尽量减少活性污泥降解的影响。结果表明,BPA在厌氧污泥上的吸附是一个快速过程。厌氧污泥在15分钟时达到了最大吸附容量的89.1%。BPA的吸附等温线通过Freundlich模型和线性吸附模型拟合良好。在10 - 30℃下,以有机碳含量归一化的吸附系数在665 - 878范围内。混合液悬浮固体(MLSS)对吸附行为有显著影响。随着MLSS的增加,吸附去除效率提高。通过测定BPA的热力学参数,可以得出BPA在厌氧污泥上的吸附主要是一个物理过程,水相和污泥相之间的分配起主导作用。解吸试验表明,BPA在厌氧污泥上的吸附部分是可逆的。

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