Dumazer G, Leda M, Nowakowski B, Lemarchand A
CNRS, Laboratoire de Physique Théorique de la Matière Condensée, Université Pierre et Marie Curie, UMR 7600, 4 place Jussieu, Case Courrier 121, 75005 Paris, France.
Phys Rev E Stat Nonlin Soft Matter Phys. 2008 Jul;78(1 Pt 2):016309. doi: 10.1103/PhysRevE.78.016309. Epub 2008 Jul 21.
We consider the two classes of exothermic chemical wave fronts, propagating toward a stable or an unstable steady state. The hydrodynamic equations for stream velocity, temperature, and concentrations are solved numerically for increasing values of the reaction heat. For a critical value of the heat release, we find a transition between a chemical front, whose speed depends on the chemical dynamics, and a generic flame, whose speed is entirely determined by heat release. We derive an analytical expression of the flame speed from the invariants of the hydrodynamic equations. This result substantiates macroscopic approaches widely used in combustion, in which the chemical models include only simplified reaction mechanisms.
