C3 钒（V）胺三酚盐配合物：卤代过氧化物酶的钒结构和功能模型。

C3 vanadium(V) amine triphenolate complexes: vanadium haloperoxidase structural and functional models.

作者信息

Mba Miriam, Pontini Marta, Lovat Silvia, Zonta Cristiano, Bernardinelli Gerald, Kündig Peter E, Licini Giulia

机构信息

Dipartimento di Scienze Chimiche, Università di Padova, via Marzolo 1, 35131 Padova, Italy.

出版信息

Inorg Chem. 2008 Oct 6;47(19):8616-8. doi: 10.1021/ic8015113. Epub 2008 Sep 6.

DOI:10.1021/ic8015113

PMID:18774797

Abstract

The C 3 vanadium(V) amine triphenolate complex 1f has been characterized as a structural and functional model of vanadium haloperoxidases. The complex catalyzes efficiently sulfoxidations at room temperature using hydrogen peroxide as the terminal oxidant, yielding the corresponding sulfoxides in quantitative yields and high selectivities (catalyst loading down to 0.01%, TONs up to 9900, and TOFs up to 8000 h (-1)) as well as bromination of 1,3,5-trimethoxybenzene (catalyst loading down to 0.05%, TONs up to 1260, and TOFs up to 220 h (-1)).

摘要

C3钒（V）胺三酚盐配合物1f已被表征为卤过氧化物酶的结构和功能模型。该配合物在室温下以过氧化氢作为终端氧化剂高效催化硫氧化反应，以定量产率和高选择性生成相应的亚砜（催化剂负载低至0.01%，TON高达9900，TOF高达8000 h⁻¹），以及催化1,3,5-三甲氧基苯的溴化反应（催化剂负载低至0.05%，TON高达1260，TOF高达220 h⁻¹）。