通过钯（II）催化的烯丙基C-H活化进行分子内/分子间直接烯丙基烷基化反应。
Intra/intermolecular direct allylic alkylation via Pd(II)-catalyzed allylic C-H activation.
作者信息
Lin Song, Song Chun-Xiao, Cai Gui-Xin, Wang Wen-Hua, Shi Zhang-Jie
机构信息
Beijing National Laboratory of Molecular Sciences, College of Chemistry and Molecular Engineering and Green Chemistry Center, Peking University, Beijing 100871, China.
出版信息
J Am Chem Soc. 2008 Oct 1;130(39):12901-3. doi: 10.1021/ja803452p. Epub 2008 Sep 9.
PMID:18778061
Abstract
The first catalytic direct alkylation of allylic C-H bonds via Pd(II)-catalysis is described in the absence of base. Polysubstituted cyclic compounds can also be constructed by the intramolecular direct allylic alkylation.
摘要
描述了在无碱条件下通过钯（II）催化进行的烯丙基C-H键的首次催化直接烷基化反应。多取代环状化合物也可通过分子内直接烯丙基烷基化反应构建。
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