Güney Kenan, Weidelener Alexander, Krampe Jörg
Stuttgart University, Institute for Sanitary Engineering, Water Quality and Solid Waste Management, Bandtäle 2, Stuttgart, Germany.
Water Res. 2008 Nov;42(18):4692-8. doi: 10.1016/j.watres.2008.08.016. Epub 2008 Aug 27.
This study was designed to solve metal ion influence problem on phosphorus recovery from digested sewage sludge as MAP. The experimental steps were proceeded to maximize MAP production and its quality. Used experimental steps were: All digested sewage sludge samples were taken from Stuttgart University sewage treatment plant for research and education (LFKW). Four different forms of LFKW digested sewage sludge were used as feeding sample. These were: original digested sludge, diluted digested sludge, centrifuged digested sludge and incinerated digested sludge. A Donnan membrane unit having a Nafion 117 (DuPont) cation exchange membrane was used to remove metal ions from the samples used. Highest metal ion removal efficiencies, which were 98%, 97%, and 80% for Al, Ca and Fe ions, respectively, were obtained from incinerated digested sludge run. Incinerated digested sludge run was used as preliminary step for MAP production and high quality MAP was produced. Produced MAP fulfils all requirements related with Düngemittelverordnung 2003 and it could be used as a fertilizer in Germany.
本研究旨在解决金属离子对消化污泥以鸟粪石形式回收磷的影响问题。进行了实验步骤以最大化鸟粪石的产量及其质量。所采用的实验步骤如下:所有消化污泥样品均取自斯图加特大学污水处理厂用于研究和教学(LFKW)。使用了四种不同形式的LFKW消化污泥作为进料样品。它们分别是:原始消化污泥、稀释消化污泥、离心消化污泥和焚烧消化污泥。使用具有Nafion 117(杜邦)阳离子交换膜的唐南膜装置从所用样品中去除金属离子。从焚烧消化污泥运行中分别获得了最高的金属离子去除效率,铝、钙和铁离子的去除效率分别为98%、97%和80%。焚烧消化污泥运行用作鸟粪石生产的初步步骤,并生产出了高质量的鸟粪石。所生产的鸟粪石满足与《肥料条例2003》相关的所有要求,并且在德国可以用作肥料。