Jin Yi-liang, Yao Jian-lin, Gu Ren-ao
Department of Chemistry, Suzhou University, Suzhou 215123, China.
Guang Pu Xue Yu Guang Pu Fen Xi. 2008 Jun;28(6):1309-11.
Using citrate as protector, Au-Ag alloy nanoparticles with different molar ratios were prepared by using hydrazine as the reducer, One plasmon band between that of monometallic Ag and Au observed in their UV-Vis spectra indicated the formation of Au-Ag alloy nanoparticles. TEM results showed diameters about 25 nm and homogeneous color of the alloy nanoparticles without clear core-shell contrast. By using Pyridine as the probe molecules, SERS studies were performed. The results indicated the spectra of Pyridine adsorbed on alloy is different from that of Ag and Au.
以柠檬酸盐为保护剂,用肼作为还原剂制备了不同摩尔比的金-银合金纳米粒子。在其紫外-可见光谱中观察到单金属银和金之间的一个等离子体带,表明形成了金-银合金纳米粒子。透射电子显微镜结果显示合金纳米粒子的直径约为25 nm,颜色均匀,没有明显的核壳对比度。以吡啶为探针分子进行了表面增强拉曼光谱研究。结果表明,吸附在合金上的吡啶光谱与银和金的不同。