在胶束体系中调节铱和钌金属表面活性剂的发射特性。
Tuning emission properties of iridium and ruthenium metallosurfactants in micellar systems.
作者信息
Guerrero-Martínez Andrés, Vida Yolanda, Domínguez-Gutiérrez David, Albuquerque Rodrigo Q, De Cola Luisa
机构信息
Physikalisches Institut, Westfälische Wilhelms-Universität Münster, Mendelstrasse 7, 48149 Münster, Germany.
出版信息
Inorg Chem. 2008 Oct 20;47(20):9131-3. doi: 10.1021/ic800849y. Epub 2008 Sep 20.
PMID:18803372
Abstract
Ruthenium metallosurfactant forms micelles that show efficient electronic energy-transfer processes in the presence of an analogous iridium complex. Modulation of the process is achieved upon incorporation of these amphiphiles into cetyltrimethylammonium bromide micelles, allowing a tuning of the two emissions.
摘要
钌金属表面活性剂形成的胶束在存在类似铱配合物的情况下表现出高效的电子能量转移过程。将这些两亲物掺入十六烷基三甲基溴化铵胶束中可实现该过程的调节，从而能够调节两种发射。
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