Zijlstra Peter, Tchebotareva Anna L, Chon James W M, Gu Min, Orrit Michel
Centre for Micro-Photonics, Faculty of Engineering and Industrial Sciences, Swinburne University of Technology, P.O. Box 218, Hawthorn, 3122, VIC Australia
Nano Lett. 2008 Oct;8(10):3493-7. doi: 10.1021/nl802480q. Epub 2008 Sep 23.
We present the first acoustic vibration measurements of single gold nanorods with well-characterized dimensions and crystal structure. The nanorods have an average size of 90 nm x 30 nm and display two vibration modes, the breathing mode and the extensional mode. Correlation between the dimensions obtained from electron microscope images and the vibrational frequencies of the same particle allows us to determine the elastic moduli for each individual nanorod. Contrary to previous reports on ensembles of gold nanorods, we find that the single particle elastic moduli agree well with bulk values.
我们展示了对尺寸和晶体结构特征明确的单个金纳米棒的首次声学振动测量。这些纳米棒的平均尺寸为90纳米×30纳米,并呈现出两种振动模式,即呼吸模式和伸展模式。通过电子显微镜图像获得的尺寸与同一粒子的振动频率之间的相关性,使我们能够确定每个单独纳米棒的弹性模量。与之前关于金纳米棒集合体的报道相反,我们发现单个粒子的弹性模量与体相值吻合得很好。