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Kagome network compounds and their novel magnetic properties.

作者信息

Pati Swapan K, Rao C N R

机构信息

Theoretical Sciences Unit, Jawaharlal Nehru Center for Advanced Scientific Research, Bangalore 560064, India.

出版信息

Chem Commun (Camb). 2008 Oct 21(39):4683-93. doi: 10.1039/b807207h. Epub 2008 Aug 27.

DOI:10.1039/b807207h
PMID:18830461
Abstract

Compounds possessing the Kagome network are truly interesting because of their unusual low-energy properties. They exhibit magnetic frustration because of the triangular lattice inherent to the hexagonal bronze structure they possess, as indeed demonstrated by some of the Fe(3+) jarosites, but this is not the general case. Kagome compounds formed by transition metal ions with varying spins exhibit novel magnetic properties, some even showing evidence for magnetic order and absence of frustration. We describe the structure and magnetic properties of this interesting class of materials and attempt to provide an explanation for the variety of properties on the basis of theoretical considerations.

摘要

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