新型六联二茂铁基六边形分子的合成及其电化学行为
Synthesis of a new family of hexakisferrocenyl hexagons and their electrochemical behavior.
作者信息
Ghosh Koushik, Zhao Yue, Yang Hai-Bo, Northrop Brian H, White Henry S, Stang Peter J
机构信息
The Department of Chemistry, University of Utah, 315 South 1400 East, RM 2020, Salt Lake City, Utah 84112, USA.
出版信息
J Org Chem. 2008 Nov 7;73(21):8553-7. doi: 10.1021/jo801692v. Epub 2008 Oct 8.
Abstract
The design and synthesis of two new hexakisferrocenyl hexagons has been achieved via coordination-driven self-assembly wherein the size and relative distribution of six ferrocene moieties has been precisely controlled. Insight into the structure and electronic properties of these supramolecules was obtained through electrochemical studies.
摘要
通过配位驱动的自组装实现了两种新型六联二茂铁六边形的设计与合成，其中六个二茂铁部分的尺寸和相对分布得到了精确控制。通过电化学研究深入了解了这些超分子的结构和电子性质。
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