一种基于四硫富瓦烯配体的自组装电活性M8L4笼。
A Self-Assembled Electro-Active M8L4 Cage Based on Tetrathiafulvalene Ligands.
作者信息
Goeb Sébastien, Bivaud Sébastien, Croué Vincent, Vajpayee Vaishali, Allain Magali, Sallé Marc
机构信息
LUNAM Université, Université d'Angers, CNRS UMR 6200, Laboratoire MOLTECH-Anjou, 2 bd Lavoisier, 49045 Angers Cedex, France.
出版信息
Materials (Basel). 2014 Jan 22;7(1):611-622. doi: 10.3390/ma7010611.
Two self-assembled redox-active cages are presented. They are obtained by coordination-driven self-assembly of a tetra-pyridile tetrathiafulvalene ligand with cis-M(dppf)(OTf)₂ (M = Pd or Pt; dppf = 1,1'-bis(diphenylphosphino)ferrocene; OTf = trifluoromethane-sulfonate) complexes. Both species are fully characterized and are constituted of 12 electro-active subunits that can be reversibly oxidized.
本文介绍了两种自组装的氧化还原活性笼。它们是通过四吡啶基四硫富瓦烯配体与顺式-M(dppf)(OTf)₂（M = Pd或Pt；dppf = 1,1'-双（二苯基膦基）二茂铁；OTf = 三氟甲磺酸盐）配合物的配位驱动自组装获得的。这两种物质都经过了全面表征，并且由12个可被可逆氧化的电活性亚基组成。
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