Ciamarra Massimo Pica, Coniglio Antonio
CNISM and Department of Information Engineering, Second University of Naples, 81031 Aversa (CE), Italy.
Phys Rev Lett. 2008 Sep 19;101(12):128001. doi: 10.1103/PhysRevLett.101.128001. Epub 2008 Sep 15.
We measure the number Omega(phi) of mechanically stable states of volume fraction phi of a granular assembly under gravity. The granular entropy S(phi)=logOmega(phi) vanishes both at high density, at phi approximately equal to phi_rcp, and a low density, at phi approximately equal to phi_rvlp, where phi_rvlp is a new lower bound we call random very loose pack. phi_rlp is the volume fraction where the entropy is maximal. These findings allow for a clear explanation of compaction experiments and provide the first first-principle definition of the random loose volume fraction. In the context of the statistical mechanics approach to static granular materials, states with phi<phi_rlp are characterized by a negative temperature.
我们测量了在重力作用下颗粒集合体体积分数为φ时机械稳定状态的数量Ω(φ)。颗粒熵S(φ)=logΩ(φ)在高密度时(φ≈φ_rcp时和低密度时,在φ≈φ_rvlp时均为零,其中φ_rvlp是我们称为随机非常松散堆积的新下限。φ_rlp是熵最大时的体积分数。这些发现为压实实验提供了清晰的解释,并给出了随机松散体积分数的首个第一性原理定义。在静态颗粒材料的统计力学方法背景下,φ<φ_rlp的状态具有负温度的特征。