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填埋前城市固体废物的生物预处理及其动力学

Bio-pretreatment of municipal solid waste prior to landfilling and its kinetics.

作者信息

Mahar Rasool Bux, Liu Jianguo, Li Huan, Nie Yongfeng

机构信息

Department of Environmental Science and Engineering, Tsinghua University, Beijing, 100084, China.

出版信息

Biodegradation. 2009 Jun;20(3):319-30. doi: 10.1007/s10532-008-9222-2. Epub 2008 Oct 16.

Abstract

The conventional landfilling does not promote sustainable waste management due to uncontrolled emissions which potentially degrade the environment. Pretreatment of municipal solid waste prior to landfilling significantly enhances waste stabilization, reduces the emissions and provides many advantages. Therefore, pretreatment of municipal solid waste methods were investigated. The major objectives of biological pretreatment are to degrade most easily degradable organic matters of MSW in a short duration under controlled conditions so as to produce desired quality for landfill. To investigate the suitable pretreatment method prior to landfilling for developing countries four pretreatment simulators were developed in the laboratory: (i) anaerobic simulator (R(1)), (ii) aerobic pretreatment simulator by natural convection of air (R(2)), (iii) aerobic pretreatment simulator by natural convection of air with leachate recirculation (R(3)) and (iv) forced aeration and leachate recirculation (R(4)). During the pretreatment organic matter, elemental composition, i.e., carbon, hydrogen, nitrogen and settlement were determined for bench scale experiments. A two-component kinetic model is proposed for the biodegradation of organic matter. Biodegradation kinetic constants were determined for readily and slowly degradable organic matter. The biodegradation of organic matter efficiency in terms of kinetic rate constants for the pretreatment simulators was observed as R(4) > R(3) > R(2) > R(1). Biodegradation rate constants for readily degradable matter in simulators R(4) and R(3) were 0.225 and 0.222 per day. R(3) and R(4) simulators were more effective in reducing methane emissions about 45% and 55%, respectively, as compared to anaerobic simulator R(1). Pretreatment of MSW, by natural convection of air with leachate recirculation R(3) is sustainable method to reduce the emissions and to stabilize the waste prior to landfilling.

摘要

传统填埋由于排放不受控制,可能会对环境造成破坏,不利于可持续的废物管理。在填埋前对城市固体废物进行预处理可显著提高废物的稳定性,减少排放,并具有诸多优势。因此,对城市固体废物的预处理方法进行了研究。生物预处理的主要目标是在受控条件下,在短时间内降解城市固体废物中最易降解的有机物,从而为填埋产生所需的质量。为了研究适合发展中国家填埋前的预处理方法,在实验室中开发了四种预处理模拟器:(i)厌氧模拟器(R(1)),(ii)通过空气自然对流的好氧预处理模拟器(R(2)),(iii)通过空气自然对流并渗滤液回流的好氧预处理模拟器(R(3)),以及(iv)强制曝气和渗滤液回流(R(4))。在预处理过程中,对实验室规模的实验测定了有机物、元素组成,即碳、氢、氮和沉降情况。提出了一个用于有机物生物降解的双组分动力学模型。确定了易降解和难降解有机物的生物降解动力学常数。观察到预处理模拟器在有机物生物降解效率方面,以动力学速率常数计为R(4) > R(3) > R(2) > R(1)。模拟器R(4)和R(3)中易降解物质的生物降解速率常数分别为每天0.225和0.222。与厌氧模拟器R(1)相比,R(3)和R(4)模拟器在减少甲烷排放方面更有效,分别约为45%和55%。通过空气自然对流并渗滤液回流的R(3)对城市固体废物进行预处理是一种可持续的方法,可减少排放并在填埋前稳定废物。

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